The results obtained by leaching stibnite with a basic solution of sodium hydrogen sulphide are presented in this paper. ... in the case of stibnite (Sb2S3), the antimony (Sb) forms stable ...
In this work, the kinetics of reductively leaching stibnite using metallic iron in a hydrochloric acid medium at varying pH, iron-to-concentrate ratio and temperature, have been …
The reductive decomposition of a stibnite (Sb 2 S 3) flotation concentrate using elemental iron was investigated in hydrochloric acid.The leaching process which proceeded via both reductive and non-oxidative chemical decomposition reactions achieved desulphurisation in excess of 95% to produce elemental and dissolved antimony species, ferrous ions and …
We have performed leaching expetiments with three reagents: 0.5 M HNO 3, 0.05 M HCl, and 0.1 M oxalic acid on stibnite powder (0.1 g Sb) to test antimony release and isotopic fractionation. …
In this work, the kinetics of reductively leaching stibnite using metallic iron in a hydrochloric acid medium at varying pH, iron-to-concentrate ratio and temperature, have been …
reaction rate between stibnite and sodium sulfide was higher than that between stibnite and sodium hydroxide. In the present paper, the purpose of this research was to investigate the effect of hydroxide type and molarity on the extraction of Sb from the stibnite concentrate. Additionally, the effect of the sulfide/sulfur-based components ...
The objective of the research study presented in this paper was to determine, under laboratory conditions, antimony recoveries in alkaline leaching of the stibnite (Sb2S3) sample originated from ...
The results show the presence of stibnite (Sb2S3) as the main primary Sb compound, bindhemite (Pb2Sb2O6(O,OH)), and minor proportions of stibiconite (Sb³⁺(Sb⁵⁺)2O6(OH)) as oxidised Sb species.
This work aims to shed light on the leaching kinetics of antimony from stibnite ore in potassium hydroxide (KOH) solution. Response surface methodology based on central composite design was used to investigate the effect of time, temperature, solid to liquid ratio (S/L), and KOH concentration as independent parameters on the leaching efficiency of antimony. …
The present work investigated the characterisation and leaching of metals from stibnite tailings. The sample analysis shown the presence of sufide minerals such as stibnite, …
This paper is concerned with the kinetics of stibnite (Sb2S3) dissolution in H2SO4-NaCl-Fe(SO4)1.5-O2 solutions. The experimental results of our study showed a positive effect from ferric ions on stibnite dissolution of up to 0.05 M. An increase in H2SO4 concentration from 0.8 to 3 M and NaCl concentration from 0 to 3 M NaCl improved the stibnite dissolution. In …
The objective of the research study presented in this paper was to determine, under laboratory conditions, antimony recoveries in alkaline leaching of the stibnite (Sb2S3) sample …
In the stibnite leaching work, Meza-Saucedo (1986) attributes the diffusion control to ionic diffusion in the liquid phase. Gudyanga et al. (1998) proposed the un-reacted shrinking core model for the reductive decomposition of stibnite flotation concentrate using Cr(II) ionic species (9), which is also a heterogeneous system. This was on the ...
Request PDF | On Jan 1, 2023, Marina Lazarov and others published Antimony release and isotope fractionation during leaching of stibnite (Sb 2 S 3 ): An experimental study | Find, read and cite ...
Request PDF | Reductive leaching of stibnite (Sb2S3) flotation concentrates using metallic iron in a hydrochloric acid medium II: Kinetics | Reductive leaching of metal sulphides is an interesting ...
The ignition temperature: According to Friedrich, stibnite, if heated in air, begins to oxidize at 290°C. if the size of a grain is 0.1 mm. in diameter; at 343°, if 0.1 to 0.2 mm.; and 430° if 0.2 mm. The fusibility of a mixture of Sb2S3 and Sb2O3 which in the form of kermesite (Sb2S3)2.Sb2O3 melts at 517°C.
In order to investigate the release process of antimony from stibnite under the leaching effect of rain and snow in Hunan Xikuangshan (XKS) mining area, some important …
The calculated values of the kinetic parameters indicate that the leaching process is controlled by both the intrinsic chemical reaction between Sb2S3 and Na2S at the liquid/solid interface and ...
Laboratory leaching tests of natural stibnite (containing Sb2S3, SiO2, ZnS and FeS2) with NaOH or NaOH - Na2S solution were carried out. Antimony recovery in NaOH leaching was lower than that with ...
We have performed leaching expetiments with three reagents: 0.5 M HNO 3, 0.05 M HCl, and 0.1 M oxalic acid on stibnite powder (0.1 g Sb) to test antimony release and isotopic fractionation. Duration of each experiment was from 10 minutes to up to 7 days at room temperature and pressure. Element concentration and isotope composition was ...
The developed process includes oxidative chlorination leaching of stibnite (Sb2S3) concentrate assaying 64.86% Sb prepared from indigenous low-grade ore containing 20.16% Sb using ferric chloride (FeCl3) solution in acidic medium as lixiviant followed by purification, precipitation and crystallization of antimony xide as end product.
The results show that stibnite (Sb2S3) can quickly transform to senarmontite (Sb2O3) in the presence of Fe2O3 and Na2CO3, and then Sb2O3 will be continuously reduced into metallic Sb.
In order to investigate the release process of antimony from stibnite under the leaching effect of rain and snow in Hunan Xikuangshan(XKS) mining area, some important environmental factors are selected: dissolved oxygen, Fe(III) and Pseudomonas sp. AO-1 (referred to as AO-1). The one-factor batch sequence experimental method is adopted to …
Stibnite (Sb2S3) occurs in nature accompanied by quartz (SiO2), pyrite (FeS2) and wurtzite (ZnS). This paper describes the behavior of antimony and some minor accompanying elements (Hg, Fe, Zn, Cu ...
This study investigated the leaching and electrowinning of antimony from a complex, high arsenic and gold-containing stibnite concentrate ore (As-Au-Sb ore) using slurry electrolysis (SE).
Semantic Scholar extracted view of "Stibnite (Sb2S3) oxidative dissolution kinetics from pH 1 to 11" by M. Biver et al. Skip to search form Skip to main content Skip to account menu ... Acid leaching and dissolution of major sulphide ore minerals: processes and galvanic effects in complex systems. P. K. Abraitis R. Pattrick G. Kelsall D. Vaughan.
The kinetics of oxidative dissolution of natural stibnite (Sb 2 S 3) under environmentally relevant conditions is investigated.The effects of hydrogen ion activity (pH 1.08–10.63), dissolved oxygen saturation (p(O 2) from 0 to 80% of atmospheric pressure), and temperature (25–48 °C) on the reaction rate were studied using a mixed flow reactor. . …
The developed process includes oxidative chlorination leaching of stibnite (Sb2S3) concentrate assaying 64.86% Sb prepared from indigenous low-grade ore containing 20.16% Sb using ferric chloride ...
This paper presents results of the laboratory investigation of alkaline leaching of stibnite that is an important mineral occuring in the antimony-bearing raw materials. The following components …